Uranium hexafluoride

Uranium hexafluoride, or UF6, is a compound used in the uranium enrichment process that produces fuel for nuclear reactors and nuclear weapons. It forms solid grey crystals at standard temperature and pressure (STP), is highly toxic, reacts violently with water and is corrosive to most metals. It reacts mildly with aluminum, forming a thin surface layer of Al2F3 that resists further reaction.

Related Topics:
Uranium - Enrichment - Nuclear reactor - Nuclear weapon - Standard temperature and pressure

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Milled uranium ore -- U3O8, or "yellowcake" -- is dissolved in nitric acid, yielding a solution of uranyl nitrate UO2(NO3)2. Pure uranyl nitrate is obtained by solvent extraction, then treated with ammonia to produce ammonium diuranate (ADU). Reduction with hydrogen gives UO2, which is converted with hydrofluoric acid (HF) to UF4. Oxidation with fluorine finally yields UF6.

Related Topics:
Yellowcake - Nitric acid - Solvent extraction - Ammonia - ADU - Hydrogen - Hydrofluoric acid - Fluorine

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It is used in both of the main uranium enrichment methods, gaseous diffusion and the gas centrifuge method, because it has a triple point at 64 °C (147 °F) and slightly higher than normal atmospheric pressure. Additionally, fluorine has only a single stable naturally occurring isotope, so isotopes of UF6 differ in their molecular weight based solely on the uranium isotope present.

Related Topics:
Gaseous diffusion - Gas centrifuge - Triple point - Fluorine - Isotope

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Gaseous diffusion requires ca. 60 times as much energy as the gas centrifuge process; even so, this is just 4% of the energy that can be produced by the resulting enriched uranium.

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Levy, J. H. et al. (1976). J. Chem. Soc., Dalton Trans. 219. (xstal structure)

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Olah, G. H.; & Welch, J. (1978). J. Am. Chem. Soc. 100: 5396. (selective oxidant of CFCs)

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