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Rydberg formula


 

The Rydberg formula (Rydberg-Ritz formula) is used in atomic physics for determining the full spectrum of light emission from hydrogen, later extended to be useful with any element.

Rydberg formula for hydrogen

: rac{1}{lambda_{mathrm{vac}}} = R_{mathrm{H}} left( rac{1}{n_1^2}- rac{1}{n_2^2} ight)

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Where

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  • lambda_{mathrm{vac}} is the wavelength of the light emitted in vacuum.
  • R_{mathrm{H}} is the Rydberg constant for hydrogen.
  • n_1 and n_2 are integers such that n_1 < n_2.
  • By setting n_1 to 1 and letting n_2 run from 2 to infinity, the spectral lines known as the Lyman series converging to 91nm are obtained, in the same manner:

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    n_1

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    n_2

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    Name

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    Converge toward

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    1

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    2 ightarrow infty

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    Lyman series

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    91nm

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    2

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    3 ightarrow infty

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    Balmer series

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    365nm

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    3

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    4 ightarrow infty

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    Paschen series

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    821nm

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    4

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    5 ightarrow infty

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    Brackett series

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    1459nm

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    5

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    6 ightarrow infty

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    Pfund series

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    2280nm

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    6

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    7 ightarrow infty

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    Humphreys series

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    3283nm

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    The Lyman series is in the ultraviolet while the Balmer series in is the visible and the Paschen, Brackett, Pfund, and Humphreys series are in the infrared.

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