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Plastic is a term that covers a range of synthetic or semisynthetic polymerization products. They are composed of organic condensation or addition polymers and may (often) contain other substances to improve performance or economics. There are few natural polymers generally considered to be "plastics". Plastics can be formed into objects or films or fibers. Their name is derived from the fact that many are malleable, having the property of plasticity. Plastics are designed with immense variation in properties such as heat tolerance, hardness, resiliency and many others. Combined with this adaptability, the general uniformity of composition and light weight of plastics ensures their use in almost all industrial segments.

Natural polymers

People have been using natural organic polymers for centuries in the form of waxes and shellacs. A plant polymer named "cellulose" provides the structural strength for natural fibers and ropes, and by the early 19th century natural rubber, tapped from rubber trees, was in widespread use.

Related Topics:
Organic - Wax - Cellulose - Natural fiber - 19th century - Rubber - Rubber tree

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Eventually, inventors learned to improve the properties of natural polymers. Natural rubber was sensitive to temperature, becoming sticky and smelly in hot weather and brittle in cold weather. In 1834, two inventors, Friedrich Ludersdorf of Germany and Nathaniel Hayward of the U.S., independently discovered that adding sulfur to raw rubber helped prevent the material from becoming sticky.

Related Topics:
Friedrich Ludersdorf - Nathaniel Hayward

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In 1839, the American inventor Charles Goodyear was experimenting with the sulfur treatment of natural rubber when, according to legend, he dropped a piece of sulfur-treated rubber on a stove. The rubber seemed to have improved properties, and Goodyear followed up with further experiments, and developed a process known as "vulcanization" that involved cooking the rubber with sulfur. Compared to untreated natural rubber, Goodyear's "vulcanized rubber" was stronger, more resistant to abrasion, more elastic, much less sensitive to temperature, impermeable to gases, and highly resistant to chemicals and electric current.

Related Topics:
1839 - Charles Goodyear - Vulcanization

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Vulcanization remains an important industrial process for the manufacture of rubber in both natural and artificial forms. Natural rubber is composed of an organic polymer named "isoprene". Vulcanization creates sulfur bonds that link separate isoprene polymers together, improving the material's structural integrity and its other properties.

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~ Table of Content ~

Introduction
Natural polymers
Cellulose-based plastics: celluloid and rayon
Bakelite (phenolic)
Polystyrene and PVC
Nylon

 

 

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