Cacodyl

Cacodyl or tetramethyldiarsine or alkarsine or Cadet's liquid (after the French chemist Louis Claude Cadet de Gassicourt) (CH3)2As?As(CH3)2 is a poisonous oily liquid with a garlicky odor. Cacodyl undergoes spontaneous combustion in dry air.

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

J?ns Jakob Berzelius coined the name kakodyl (later changed to cacodyl) for the dimethylarsinyl radical, (CH3)2As, from the Greek kakodes (evil-smelling) and hyle (matter).

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

It was investigated by Edward Frankland and Robert Bunsen and is considered one of the earliest organometallic compounds ever discovered. It was originally made from arsenic distilled with potassium acetate.

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

In Bunsen's words "the smell of this body produces instantaneous tingling of the hands and feet, and even giddiness and insensibility...It is remarkable that when one is exposed to the smell of these compounds the tongue becomes covered with a black coating, even when no further evil effects are noticeable".

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

Work on cacodyl led Bunsen to the postulation of methyl radicals.

~ ~ ~ ~ ~ ~ ~ ~ ~ ~

Edward Frankland: Sir Edward Frankland (January 18, 1825 – August 9, 1899) was an English chemist....

Robert Bunsen: Robert Wilhelm Bunsen (31 March, 1811 – 16 August, 1899) was a German chemist. He perfected the burner that was named after him, invented by British chemist/physicist Michael Faraday, and worked on emission spectroscopy of heated elements....

Organometallic: redirect organometallic chemistry...