Avogadro's number

Avogadro's number, also called Avogadro's constant (NA) is a large constant used in chemistry and physics. Avogadro's number is formally defined as the number of carbon-12 atoms in 12 grams (0.012 kg) of carbon-12, which is approximately 6.022 × 1023. Historically, carbon-12 was chosen as the reference substance because its atomic mass could be measured particularly accurately.

Connection to masses of protons and neutrons

A carbon-12 atom consists of 6 protons and 6 neutrons (which have approximately the same mass) and 6 electrons (whose mass is negligible in comparison). One could therefore think that NA is the number of protons or neutrons that have a mass of 1 gram. While this is approximately correct, the mass of a free proton is 1.00727 amu, so a mole of protons would actually have a mass of 1.00727 g. Similarly, a mole of neutrons has a mass of 1.00866 g. Clearly, 6 moles of protons combined with six moles of neutrons would have a mass greater than 12 g. So, you might ask how one mole of carbon-12 atoms, which should consist of 6 moles each of protons, neutrons, and electrons could possibly have a mass of only 12 g? What happened to the excess mass? The answer is related to the equivalence of matter and energy discovered by Albert Einstein as part of the theory of special relativity. When an atom is formed, the protons and neutrons in the nucleus are bound together by the strong nuclear force. This binding results in the formation of a low energy state and is accompanied by a large release of energy. Since energy is equivalent to mass, the released energy corresponds to a loss in the mass of the nucleus relative to that of the separated protons and neutrons. Thus, protons and neutrons in the nucleus have masses that are less (about 0.7 percent less) than free protons and neutrons. The precise amount of mass loss is related to the binding energy of the nucleus and varies depending on the type of atom.

Related Topics:
Proton - Neutron - Electron - Equivalence of matter and energy - Albert Einstein - Special relativity - Strong nuclear force

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One may therefore say that NA is approximately the number of nuclear neutrons or protons that have a mass of 1 gram. This is approximate because the precise mass of a nuclear proton or neutron depends on the composition of the nucleus. For example, iron nucleons will have a significantly lower mass than those in hydrogen or plutonium.

Related Topics:
Iron - Hydrogen - Plutonium

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