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Aluminium


 

Aluminium or aluminum (Symbol Al) (see the spelling section below) is a silvery and ductile member of the poor metal group of chemical elements. Its atomic number is 13. Aluminium is found primarily as the ore bauxite and is remarkable for its resistance to oxidation (due to the phenomenon of passivation), its strength, and its light weight. Aluminium is used in many industries to make millions of different products and is very important to the world economy. Structural components made from aluminium are vital to the aerospace industry and very important in other areas of transportation and building in which light weight, durability, and strength are needed.

Applications

Whether measured in terms of quantity or value, the use of aluminium exceeds that of any other metal except iron, and it is important in virtually all segments of the world economy.

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Pure aluminium has a low tensile strength, but readily forms alloys with many elements such as copper, zinc, magnesium, manganese and silicon. When combined with thermo-mechanical processing these aluminium alloys display a marked improvement in mechanical properties. Aluminium alloys form vital components of aircraft and rockets as a result of their high strength to weight ratio.

Related Topics:
Tensile strength - Alloy - Aircraft - Rocket

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When aluminium is evaporated in a vacuum it forms a coating that reflects both visible light and radiant heat. These coatings form a thin layer of protective aluminium oxide that does not deteriorate as silver coatings do. In particular, nearly all modern mirrors are made using a thin reflective coating of aluminium on the back surface of a sheet of float glass. Telescope mirrors are also coated with a thin layer of aluminium, but are front coated to avoid internal reflections even though this makes the surface more susceptible to damage.

Related Topics:
Visible light - Radiant heat - Silver - Mirror - Float glass - Telescope

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Some of the many uses for aluminium are in:

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  • Transportation (automobiles, airplanes, trucks, railroad cars, marine vessels, etc.)
  • Packaging (cans, foil, etc.)
  • Water treatment
  • Construction (windows, doors, siding, building wire, etc.
  • Consumer durable goods (appliances, cooking utensils, etc.)
  • Electrical transmission lines (aluminium conductors are half the weight of copper for equal conductivity and lower in pricehttp://www.metalprices.com)
  • Machinery.
  • Although non-magnetic itself, aluminium is used in MKM steel and Alnico magnets.
  • Super Purity Aluminium (SPA, 99.980% to 99.999% Al) is used in electronics and CDs.
  • Powdered aluminium is commonly used for silvering in paint. Aluminium flakes may also be included in undercoat paints, particularly wood primer — on drying, the flakes overlap to produce a water resistant barrier.
  • Anodized aluminium is more stable to further oxidation, and is used in various fields of construction.
  • Most modern computer CPU heat sinks are made of aluminium due to its ease of manufacture and good heat conductivity. Copper heat sinks are smaller although more expensive and harder to manufacture.
  • Aluminium oxide, alumina, is found naturally as corundum, emery, ruby, and sapphire and is used in glass making. Synthetic ruby and sapphire are used in lasers for the production of coherent light.

    Related Topics:
    Alumina - Corundum - Emery - Ruby - Sapphire - Glass - Laser - Coherent light

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    Aluminium oxidizes very energetically and as a result has found use in solid rocket fuels, thermite, and other pyrotechnic compositions.

    Related Topics:
    Solid rocket - Thermite - Pyrotechnic

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Engineering use

Improper use of aluminium can result in problems, particularly in contrast to iron or steel, which appear "better behaved" to the intuitive designer, mechanic, or technician. The reduction by two thirds of the weight of an aluminium part compared to a similarly sized iron or steel part seems enormously attractive, but it should be noted that it is accompanied by a reduction by two thirds in the stiffness of the part. Therefore, although direct replacement of an iron or steel part with a duplicate made from aluminium may still give acceptable strength to withstand peak loads, the increased flexibility will cause three times more deflection in the part.

Related Topics:
Iron - Steel

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Where failure is not an issue but excessive flex is undesirable due to requirements for precision of location or efficiency of transmission of power, simple replacement of steel tubing with similarly sized aluminium tubing will result in a degree of flex which is undesirable; for instance, the increased flex under operating loads caused by replacing steel bicycle frame tubing with aluminium tubing of identical dimensions will cause misalignment of the power-train as well as absorbing the operating force. To increase the rigidity by increasing the thickness of the walls of the tubing increases the weight proportionately, so that the advantages of lighter weight are lost as the rigidity is restored.

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Aluminium can best be used by redesigning the part to suit its characteristics; for instance making a bicycle of aluminium tubing which has an oversize diameter rather than thicker walls. In this way, rigidity can be restored or even enhanced without increasing weight. The limit to this process is the increase in susceptibility to what is termed "crippling" failure, where the deviation of the force from any direction other than directly along the axis of the tubing causes folding of the walls of the tubing. For instance, a common aluminium soft drink can should be able to support an enormous weight directly along its axis; in practice, however, the walls of the can buckle, crumple, and/or fold up under even a mild force, due to minute deviations from the precise axial direction, making possible the common pastime of flattening an empty can by slamming it against one's forehead.

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The latest models of the Corvette automobile, among others, are a good example of redesigning parts to make best use of aluminium's advantages. The aluminium chassis members and suspension parts of these cars have large overall dimensions for stiffness but are lightened by reducing cross-sectional area and removing unneeded metal; as a result, they are not only equally or more durable and stiff as the usual steel parts, but they possess an airy gracefulness which most people find attractive. Similarly, aluminium bicycle frames can be optimally designed so as to provide rigidity where required, yet have flexibility in terms of absorbing the shock of bumps from the road and not transmitting them to the rider.

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The strength and durability of aluminium varies widely, not only as a result of the components of the specific alloy, but also as a result of the particular manufacturing process; for this reason, it has from time to time gained a bad reputation. For instance, a high frequency of failure in many early aluminium bicycle frames in the 1970s resulted in just such a poor reputation; with a moment's reflection, however, the widespread use of aluminium components in the aerospace and automotive high performance industries, where huge stresses are undergone with vanishingly small failure rates, proves that properly built aluminium bicycle components should not be unusually unreliable, and this has subsequently proved to be the case.

Related Topics:
1970 - Aerospace

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Similarly, use of aluminium in automotive applications, particularly in engine parts which must survive in difficult conditions, has benefited from development over time. An Audi engineer commented about the V12 engine, producing over 500 horsepower (370 kW), of an Auto Union race car of the 1930s which was recently restored by the Audi factory, that the aluminium alloy of which the engine was constructed would today be used only for lawn furniture and the like. Even the aluminium cylinder heads and crankcase of the Corvair, built as recently as the 1960s, earned a reputation for failure and stripping of threads in holes, even as large as spark plug holes, which is not seen in current aluminium cylinder heads.

Related Topics:
Audi - Auto Union race car - 1930s - Cylinder head - Crankcase - Corvair - 1960s - Thread - Spark plug

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Often, aluminium's sensitivity to heat must also be considered. Even a relatively routine procedure such as welding is complicated by the fact that aluminium will melt long before it gets even dully red hot; therefore, unlike steel or iron, where the experienced welder can know from its hue how close the metal is to the melting point, welding aluminium requires a degree of expertise incorporating an almost intuitive sense of the metal's temperature, or else the part suddenly and without warning melts into a puddle. Aluminium also will accumulate internal stresses and strains under conditions of overheating; while not immediately obvious, the tendency of the metal to "creep" under sustained stresses results in delayed distortions, for instance the commonly observed warping or cracking of aluminium automobile cylinder heads after an engine is overheated, sometimes as long as years later, or the tendency of welded aluminium bicycle frames to gradually twist out of alignment from the stresses accumulated during the welding process. For this reason, many uses of aluminium in the aerospace industry avoid heat altogether by joining parts using adhesives; this was also used for some of the early aluminium bicycle frames in the 1970s, with unfortunate results when the aluminium tubing corroded slightly, loosening the bond of the adhesive and leading to failure of the frame. Stresses from overheating aluminium can be relieved by heat-treating the parts in an oven and gradually cooling, in effect annealing the stresses; this can also result, however, in the part becoming distorted as a result of these stresses, so that such heat-treating of welded bicycle frames, for instance, results in a significant fraction becoming misaligned. If the misalignment is not too severe, once cooled they can be bent back into alignment with no negative consequences; of course, if the frame is properly designed for rigidity (see above), this will require enormous force.

Related Topics:
Adhesive - Annealing

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Household wiring

Because of its high conductivity and relatively low price compared to copper at the time, aluminium was introduced for household electrical wiring to a large degree in the United States in the 1960s. Unfortunately, many of the wiring fixtures used with aluminium wiring at the time were not designed to accept aluminium wire; i.e. the greater coefficient of thermal expansion of aluminium, causing the wire to expand and contract where it was captured under the head of a dissimilar metal screw connection, eventually working a degree of looseness into the connection; the tendency of pure aluminium to "creep" under steady sustained pressure (to a greater degree as the temperature rises), again producing a degree of looseness in an initially tight connection; and the tendency of the dissimilar metals to corrode when placed in direct contact, which will increase the resistance in such a loosened connection. In combination, these properties resulted in a tendency of the connections between electrical fixtures and aluminium wiring to overheat to the point where the material of the walls could ignite, and fires occurred. As a result, aluminium household wiring has become unpopular, and in many jurisdictions is not permitted in very small sizes in new construction. However, existing aluminium wiring can be safely used with fixtures whose connections are designed to avoid this loosening/overheating runaway cycle; older fixtures of this type are marked "Al/Cu", while newer ones are marked "CO/ALR". Otherwise, aluminium wiring can be terminated by crimping it to a short "pigtail" of copper wire, which can be treated as any other copper wire; a properly done crimp, requiring the high pressure produced by the proper tool, is tight enough not only to eliminate any thermal expansion of the aluminium, but also to exclude any atmospheric oxygen and thus prevent corrosion between dissimilar metals. New alloys are used for aluminium building wire today in combination with aluminium terminations. Connections made with these standard industry products are as safe and reliable as copper connections.

Related Topics:
Copper - Electrical wiring - United States - Coefficient of thermal expansion - Screw - Electrical fixture - Crimp - Pigtail

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